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Alkanes & alkenes: IGCSE Chemistry questions with answers Free Alkanes & alkenes questions for IGCSE Chemistry (0620), part of Organic chemistry. Each question has the answer and the marking points an examiner would look for.
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Alkanes & alkenes practice questions Question 1 Multiple choice · 1 mark A* challenge
Ethene reacts separately with bromine, with steam and with hydrogen. Which row shows the products?
with bromine with steam with hydrogen A CH2 BrCH2 Br CH3 COOH CH3 CH3 B CH3 CH2 Br CH3 CH2 OH CH3 CH3 C CH2 BrCH2 Br CH3 CH2 OH CH3 CH3 D CH2 BrCH2 Br CH3 CH2 OH CH2 CH2
Show answer Answer: C
Question 2 Multiple choice · 1 mark A* challenge
Ethanoic acid reacts with propan-1-ol to form an ester. What are the name and the structural formula of the ester?
name structural formula A propyl ethanoate CH3 COOCH2 CH2 CH3 B ethyl propanoate CH3 CH2 COOCH2 CH3 C ethyl propanoate CH3 COOCH2 CH2 CH3 D propyl ethanoate CH3 CH2 COOCH2 CH3
Show answer Answer: A
Question 3 Structured · 6 marks
Fig. 3.1 shows the displayed formula of compound Q.
C C C H H H H H H Fig. 3.1 (b) State the homologous series to which Q belongs.
[1] (c) Write the molecular formula of Q.
[1] (d) Describe a test to distinguish an alkane from an alkene. Give the result for each.
[3] Show answers and mark scheme Part Answer and marking points Marks (a) propenepropene B1
1 (b) alkenesalkenes B1
1 (c) C3 H6 C3 H6 B1
1 (d) Bromine water: alkene decolourises it (orange to colourless); alkane: stays orangeaqueous bromine / bromine water B1 alkene: orange → colourless B1 alkane: remains orange B1
3
Question 4 Structured · 6 marks
Ethene can be made by cracking long-chain alkanes.
(a) Describe the conditions used for cracking.
[2] (b) Explain why cracking is important to the petrochemical industry.
[2] (c) Describe a test to distinguish ethene from ethane.
[2] Show answers and mark scheme Part Answer and marking points Marks (a) high temperature; catalysthigh temperature B1 catalyst (e.g. silica/alumina) or steam B1
2 (b) supply of short-chain fuels and alkenesthere is more demand for short-chain alkanes (petrol) than supply B1 it also produces alkenes for making polymers B1
2 (c) bromine water decolourises with etheneadd bromine water B1 ethene decolourises it (orange to colourless), ethane does not B1
2
Question 5 Structured · 3 marks
Alkanes are used as fuels.
(a) Write a balanced equation for the complete combustion of propane, C₃H₈.
[2] (b) State what is meant by a saturated hydrocarbon.
[1] Show answers and mark scheme Part Answer and marking points Marks (a) C₃H₈ + 5O₂ → 3CO₂ + 4H₂Ocorrect formulae B1 balanced B1
2 (b) only single C–C bondscontains only single carbon–carbon bonds B1
1
Question 6 Structured · 14 marks A* challenge
Large alkane molecules such as C10 H22 are cracked to make smaller, more useful molecules.
(a) State the conditions used for catalytic cracking.
[2] (b) One molecule of C10 H22 is cracked into one molecule of octane, C8 H18 , and ethene only. Write the equation.
[2] (c) Describe a test that shows that ethene is unsaturated. Give the result.
[2] (d) Ethene reacts with steam to make ethanol. State the conditions and the type of reaction.
[3] (e) Ethanol is oxidised to ethanoic acid, which then reacts with ethanol. Name the product and draw its displayed formula.
[3] (f) Draw one repeat unit of the addition polymer made from propene, CH3 CH=CH2 .
[2] Show answers and mark scheme Part Answer and marking points Marks (a) high temperature and a catalyst (e.g. 600–700 °C, alumina/silica/zeolite)high temperature B1 catalyst B1
2 (b) C10 H22 → C8 H18 + 1C2 H4 correct formulae B1 balanced with 1C2 H4 B1
2 (c) Add bromine water: orange to colourlessbromine (water) B1 orange → colourless (decolourised) B1
2 (d) 300 °C, 60 atm, phosphoric acid catalyst; addition (hydration)temperature ~300 °C and pressure ~60 atm B1 (phosphoric) acid catalyst B1 addition B1
3 (e) ethyl ethanoate, CH3 COOCH2 CH3 ethyl ethanoate B1 ester linkage –COO– shown B1 all atoms and bonds correct B1
3 (f) –[CH2 –CH(CH3 )]– with continuation bondstwo carbons in chain with CH3 side group B1 continuation bonds at both ends B1
2
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