IGCSE · Chemistry 0620 · Organic chemistry

Alkanes & alkenes: IGCSE Chemistry questions with answers

Free Alkanes & alkenes questions for IGCSE Chemistry (0620), part of Organic chemistry. Each question has the answer and the marking points an examiner would look for.

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Alkanes & alkenes practice questions

Question 1Multiple choice · 1 markA* challenge

Ethene reacts separately with bromine, with steam and with hydrogen.
Which row shows the products?

with brominewith steamwith hydrogen
ACH2BrCH2BrCH3COOHCH3CH3
BCH3CH2BrCH3CH2OHCH3CH3
CCH2BrCH2BrCH3CH2OHCH3CH3
DCH2BrCH2BrCH3CH2OHCH2CH2
Show answer

Answer: C

Question 2Multiple choice · 1 markA* challenge

Ethanoic acid reacts with propan-1-ol to form an ester.
What are the name and the structural formula of the ester?

namestructural formula
Apropyl ethanoateCH3COOCH2CH2CH3
Bethyl propanoateCH3CH2COOCH2CH3
Cethyl propanoateCH3COOCH2CH2CH3
Dpropyl ethanoateCH3CH2COOCH2CH3
Show answer

Answer: A

Question 3Structured · 6 marks

Fig. 3.1 shows the displayed formula of compound Q.

CCCHHHHHH
Fig. 3.1
(a)

Name compound Q.

[1]
(b)

State the homologous series to which Q belongs.

[1]
(c)

Write the molecular formula of Q.

[1]
(d)

Describe a test to distinguish an alkane from an alkene. Give the result for each.

[3]
Show answers and mark scheme
PartAnswer and marking pointsMarks
(a)propene
propene B1
1
(b)alkenes
alkenes B1
1
(c)C3H6
C3H6 B1
1
(d)Bromine water: alkene decolourises it (orange to colourless); alkane: stays orange
aqueous bromine / bromine water B1
alkene: orange → colourless B1
alkane: remains orange B1
3
Question 4Structured · 6 marks

Ethene can be made by cracking long-chain alkanes.

(a)

Describe the conditions used for cracking.

[2]
(b)

Explain why cracking is important to the petrochemical industry.

[2]
(c)

Describe a test to distinguish ethene from ethane.

[2]
Show answers and mark scheme
PartAnswer and marking pointsMarks
(a)high temperature; catalyst
high temperature B1
catalyst (e.g. silica/alumina) or steam B1
2
(b)supply of short-chain fuels and alkenes
there is more demand for short-chain alkanes (petrol) than supply B1
it also produces alkenes for making polymers B1
2
(c)bromine water decolourises with ethene
add bromine water B1
ethene decolourises it (orange to colourless), ethane does not B1
2
Question 5Structured · 3 marks

Alkanes are used as fuels.

(a)

Write a balanced equation for the complete combustion of propane, C₃H₈.

[2]
(b)

State what is meant by a saturated hydrocarbon.

[1]
Show answers and mark scheme
PartAnswer and marking pointsMarks
(a)C₃H₈ + 5O₂ → 3CO₂ + 4H₂O
correct formulae B1
balanced B1
2
(b)only single C–C bonds
contains only single carbon–carbon bonds B1
1
Question 6Structured · 14 marksA* challenge

Large alkane molecules such as C10H22 are cracked to make smaller, more useful molecules.

(a)

State the conditions used for catalytic cracking.

[2]
(b)

One molecule of C10H22 is cracked into one molecule of octane, C8H18, and ethene only. Write the equation.

[2]
(c)

Describe a test that shows that ethene is unsaturated. Give the result.

[2]
(d)

Ethene reacts with steam to make ethanol. State the conditions and the type of reaction.

[3]
(e)

Ethanol is oxidised to ethanoic acid, which then reacts with ethanol. Name the product and draw its displayed formula.

[3]
(f)

Draw one repeat unit of the addition polymer made from propene, CH3CH=CH2.

[2]
Show answers and mark scheme
PartAnswer and marking pointsMarks
(a)high temperature and a catalyst (e.g. 600–700 °C, alumina/silica/zeolite)
high temperature B1
catalyst B1
2
(b)C10H22 → C8H18 + 1C2H4
correct formulae B1
balanced with 1C2H4 B1
2
(c)Add bromine water: orange to colourless
bromine (water) B1
orange → colourless (decolourised) B1
2
(d)300 °C, 60 atm, phosphoric acid catalyst; addition (hydration)
temperature ~300 °C and pressure ~60 atm B1
(phosphoric) acid catalyst B1
addition B1
3
(e)ethyl ethanoate, CH3COOCH2CH3
ethyl ethanoate B1
ester linkage –COO– shown B1
all atoms and bonds correct B1
3
(f)–[CH2–CH(CH3)]– with continuation bonds
two carbons in chain with CH3 side group B1
continuation bonds at both ends B1
2

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Original Cambridge-style practice questions written for mentorriyaz.in. These are not Cambridge past paper questions, and this site is not affiliated with or endorsed by Cambridge University Press & Assessment. Updated 2026-11-04. Paper generator · mentorriyaz.in