IGCSE · Chemistry 0620 · Topic

Organic Chemistry: IGCSE Chemistry questions and answers

10 free IGCSE Chemistry Organic Chemistry questions written in the style of Cambridge Chemistry papers: 3 multiple-choice and 7 structured, each with its answer and mark scheme. 4 of them are A* challenge questions, built to catch the mistakes strong students still make.

This topic covers Formulae, functional groups & naming, Alkanes & alkenes, Alcohols & carboxylic acids, Polymers. Work through the questions below, then generate a full Organic Chemistry paper with a fresh set every time.

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Organic chemistry sub-topics

Organic chemistry practice questions

Question 1Multiple choice · 1 markA* challenge

Ethanol is made by fermentation and by the catalytic addition of steam to ethene.
Which row is correct?

fermentationaddition of steam
Acontinuous processuses a renewable raw material
Buses a renewable raw materialcontinuous process
Cproduces pure ethanoluses yeast
Dhigh temperature and pressurebatch process
Show answer

Answer: B

Question 2Multiple choice · 1 markA* challenge

How many structural isomers have the molecular formula C5H12?

  1. A 1
  2. B 2
  3. C 3
  4. D 5
Show answer

Answer: C

Question 3Multiple choice · 1 markA* challenge

Nylon and PET are condensation polymers. Poly(ethene) is an addition polymer.
1    Poly(ethene) is made from monomers that contain C=C double bonds.
2    Nylon is a polyester.
3    Addition polymerisation forms water as a second product.
Which statements are correct?

  1. A 1, 2 and 3
  2. B 1 and 2 only
  3. C 1 and 3 only
  4. D 1 only
Show answer

Answer: D

Question 4Structured · 5 marksA* challenge

Ethanol can be made by fermentation or from ethene.

(a)

Describe the conditions for fermentation.

[3]
(b)

Give one advantage and one disadvantage of fermentation compared with hydration of ethene.

[2]
Show answers and mark scheme
PartAnswer and marking pointsMarks
(a)yeast, 25–35 °C, no oxygen
glucose solution with yeast B1
warm (about 25–35 °C) B1
absence of oxygen (anaerobic) B1
3
(b)renewable; slow / impure
advantage: uses renewable resources / low temperature B1
disadvantage: slow / batch process / impure ethanol B1
2
Question 5Structured · 3 marks

Alkanes are used as fuels.

(a)

Write a balanced equation for the complete combustion of propane, C₃H₈.

[2]
(b)

State what is meant by a saturated hydrocarbon.

[1]
Show answers and mark scheme
PartAnswer and marking pointsMarks
(a)C₃H₈ + 5O₂ → 3CO₂ + 4H₂O
correct formulae B1
balanced B1
2
(b)only single C–C bonds
contains only single carbon–carbon bonds B1
1
Question 6Structured · 14 marks

This question is about alcohols and carboxylic acids.

Ethanol can be made by the fermentation of glucose.

(a)(i)

Write the equation for the fermentation of glucose, C₆H₁₂O₆.

[2]
(ii)

State two conditions needed for fermentation.

[2]
(iii)

Calculate the maximum mass of ethanol made from 45 g of glucose. [Mᵣ: glucose, 180; ethanol, 46]

[2]
(iv)

Explain why fermentation stops when the ethanol concentration reaches about 15%.

[1]
(b)

Ethanol is oxidised to ethanoic acid by acidified potassium manganate(VII). State the colour change and the type of reaction.

[2]
(c)

Ethanoic acid reacts with propan-1-ol in the presence of an acid catalyst. Name the ester formed and give its structural formula.

[2]
(d)

Ethanoic acid reacts with sodium carbonate. Write the equation and describe what is seen.

[3]
Show answers and mark scheme
PartAnswer and marking pointsMarks
(a)(i)C₆H₁₂O₆ → 2C₂H₅OH + 2CO₂
C₂H₅OH and CO₂ as products B1
balanced B1
2
(ii)yeast; about 30 °C; absence of oxygen
Any 2 of: yeast; 25–35 °C; absence of oxygen / anaerobic; aqueous solution B2
2
(iii)23.0 g
moles glucose = 0.250, moles ethanol = 0.500 M1
23.0 g A1
2
(iv)yeast is killed by the ethanol
the ethanol kills / denatures the yeast (enzymes) B1
1
(b)purple to colourless; oxidation
purple to colourless B1
oxidation B1
2
(c)propyl ethanoate, CH₃COOC₃H₇
propyl ethanoate B1
CH₃COOC₃H₇ B1
2
(d)2CH₃COOH + Na₂CO₃ → 2CH₃COONa + H₂O + CO₂; fizzing
correct products CH₃COONa, H₂O, CO₂ B1
balanced B1
effervescence / fizzing / solid dissolves B1
3
Question 7Structured · 3 marks

Ethanol is used as a fuel and a solvent.

(a)

Write a balanced equation for the complete combustion of ethanol.

[2]
(b)

Give one use of ethanol other than as a fuel.

[1]
Show answers and mark scheme
PartAnswer and marking pointsMarks
(a)C₂H₅OH + 3O₂ → 2CO₂ + 3H₂O
correct formulae B1
balanced B1
2
(b)solvent; drinks; disinfectant
solvent / in alcoholic drinks / antiseptic B1
1
Question 8Structured · 4 marks

Organic compounds are named according to their functional groups.

(a)

Name the functional group in carboxylic acids and in alcohols.

[2]
(b)

Give the name of CH₃CH₂CH₂OH.

[1]
(c)

Give the molecular formula of butene.

[1]
Show answers and mark scheme
PartAnswer and marking pointsMarks
(a)–COOH; –OH
carboxylic acid: –COOH B1
alcohol: –OH B1
2
(b)propan-1-ol
propan-1-ol (propanol) B1
1
(c)C₄H₈
C₄H₈ B1
1
Question 9Structured · 5 marks

Ethanol, C₂H₅OH, and ethene, C₂H₄, are organic compounds.

(a)

Name the homologous series to which each belongs.

[2]
(b)

State two characteristics of a homologous series.

[2]
(c)

Draw the displayed formula of ethanol.

[1]
Show answers and mark scheme
PartAnswer and marking pointsMarks
(a)alcohols; alkenes
ethanol: alcohols B1
ethene: alkenes B1
2
(b)same general formula; same functional group; similar chemical properties; trend in physical properties
Any 2 of: same general formula; same functional group; similar chemical properties; gradual change in physical properties B2
2
(c)H–C(H)(H)–C(H)(H)–O–H
correct displayed formula showing all atoms and bonds B1
1
Question 10Structured · 6 marks

Ethene can be made by cracking long-chain alkanes.

(a)

Describe the conditions used for cracking.

[2]
(b)

Explain why cracking is important to the petrochemical industry.

[2]
(c)

Describe a test to distinguish ethene from ethane.

[2]
Show answers and mark scheme
PartAnswer and marking pointsMarks
(a)high temperature; catalyst
high temperature B1
catalyst (e.g. silica/alumina) or steam B1
2
(b)supply of short-chain fuels and alkenes
there is more demand for short-chain alkanes (petrol) than supply B1
it also produces alkenes for making polymers B1
2
(c)bromine water decolourises with ethene
add bromine water B1
ethene decolourises it (orange to colourless), ethane does not B1
2

Other IGCSE Chemistry topics

Frequently asked questions

What is in IGCSE Chemistry Organic Chemistry?

In the 0620 syllabus, Organic Chemistry covers Formulae, functional groups & naming, Alkanes & alkenes, Alcohols & carboxylic acids, Polymers.

Where can I get Organic Chemistry questions with mark schemes?

This page has 10 Organic Chemistry questions with answers. For more, the free generator on mentorriyaz.in builds a new Organic Chemistry paper with a full mark scheme each time you click.

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Original Cambridge-style practice questions written for mentorriyaz.in. These are not Cambridge past paper questions, and this site is not affiliated with or endorsed by Cambridge University Press & Assessment. Updated 2026-11-04. Paper generator · mentorriyaz.in