E.3 Radioactive decay
Isotopes and nuclear stability, the strong force, mass defect and binding energy, the binding-energy-per-nucleon curve, alpha, beta and gamma decay, neutrinos, half-life and activity, background radiation, and (HL) the decay constant and exponential decay.
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In 30 seconds
- Protons repel each other, but the strong nuclear force (attractive, very short range) holds the nucleus together. Too many protons or neutrons makes a nucleus unstable.
- A nucleus has less mass than its separate nucleons. This mass defect Δm is the binding energy E = Δmc2. Iron-56 has the highest binding energy per nucleon: the most stable.
- Unstable nuclei decay randomly and spontaneously by α, β−, β+ or γ emission. Half-life is the time for half the nuclei (or the activity) to go.
- HL: N = N0e−λt, A = λN and T½ = ln 2/λ; the β energy spectrum as evidence for neutrinos.
By the end you can
- Use nuclear notation to write balanced decay equations for α, β−, β+ and γ.
- Describe the strong force and use an N–Z chart to predict decay type.
- Calculate mass defect and binding energy, and interpret the binding-energy-per-nucleon curve.
- Compare the properties of α, β and γ radiation and describe background radiation.
- Use half-life with graphs and calculations.
- Use the decay constant, N = N0e−λt and A = λN. HL
- Explain how the β energy spectrum shows that neutrinos exist. HL
1Nuclear stability
- Strong nuclear force: attractive between all nucleons, about 10−15 m range, repulsive at even shorter distances. Light nuclei are stable with N ≈ Z; heavy nuclei need N > Z.
2Mass defect and binding energy
Binding energy — the energy needed to separate a nucleus completely into its individual protons and neutrons (equivalently, the energy released when it forms).
Find the binding energy per nucleon of helium-4 (nuclear mass 4.001506 u; mp = 1.007276 u, mn = 1.008665 u).
- mass of nucleons = 2(1.007276) + 2(1.008665) = 4.031882 u M1
- Δm = 4.031882 − 4.001506 = 0.030376 u A1
- E = 0.030376 × 931.5 = 28.3 MeV, so 7.07 MeV per nucleon A1
3Types of decay
| Type | What leaves | Change | Example |
|---|---|---|---|
| alpha α | 42He nucleus | A − 4, Z − 2 | 23892U → 23490Th + 42α |
| beta-minus β− | electron + antineutrino | n → p: A same, Z + 1 | 146C → 147N + 0−1e + ν̄ |
| beta-plus β+ | positron + neutrino | p → n: A same, Z − 1 | 2211Na → 2210Ne + 0+1e + ν |
| gamma γ | photon | no change in A or Z | after α or β, the excited nucleus drops to its ground state |
- Balancing: both A and Z must add up on each side. Charge, nucleon number and (with the neutrino) lepton number are conserved.
| α | β | γ | |
|---|---|---|---|
| ionising | strongly | moderately | weakly |
| range in air | a few cm | about 1 m | very long (intensity falls with distance) |
| stopped by | paper or skin | a few mm of aluminium | reduced by cm of lead |
| deflected by fields | yes (positive) | yes (opposite way, more) | no |
- Background radiation comes from rocks (radon gas is the largest part), cosmic rays, food, medical uses and nuclear industry. Subtract it from every count rate you measure.
4Half-life
Half-life T½ — the time for half of the undecayed nuclei in a sample to decay, or for the activity to halve.
Activity A — the number of decays per second, in becquerels (Bq).
A sample of 80 mg has a half-life of 6.0 hours. How much is left after one day?
- 24 h = 4 half-lives M1
- 80 → 40 → 20 → 10 → 5.0 mg A1
- Random: you cannot predict when a given nucleus decays, only the probability. Spontaneous: temperature, pressure and chemistry do not change it.
5The decay constant HL
A wooden object has 40 % of the carbon-14 activity of living wood (T½ = 5730 years). How old is it?
- λ = ln 2/5730 = 1.21 × 10−4 yr−1 M1
- 0.40 = e−λt ⇒ t = ln(1/0.40)/λ M1
- t = 7.6 × 103 years A1
- Very long half-lives (uranium, about 109 years) are found from A = λN: count the activity and the number of nuclei (from the mass), then λ = A/N.
- Neutrino evidence: β particles have a continuous range of energies up to a maximum. Energy and momentum are conserved only if a third, almost undetectable particle (the neutrino, or antineutrino in β−) takes the rest.
Test yourself — cover the answers first
Quick check
- What force holds the nucleus together?
- What changes in β− decay?
- Which radiation is most ionising?
- A count rate falls from 800 to 100 in 30 minutes. What is the half-life?
- Which nucleus has the highest binding energy per nucleon?
- HL Find λ for a half-life of 8.0 days, in s−1.
Exam-style
- Complete: 22688Ra → ? + 42He, and 9038Sr → ? + 0−1e + ν̄.
- HL A source has activity 4.0 × 105 Bq and half-life 30 years. How many radioactive nuclei does it contain?
Show answers
- the strong nuclear force
- a neutron becomes a proton: Z rises by 1, A stays the same
- alpha
- 3 half-lives, so 10 minutes
- iron-56 (or nickel-62)
- ln 2/(8.0 × 86 400) = 1.0 × 10−6 s−1
- 22286Rn
9039Y - λ = ln 2/(30 × 3.15 × 107) = 7.3 × 10−10 s−1
N = A/λ = 4.0 × 105/7.3 × 10−10
= 5.5 × 1014 nuclei
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